{"id":553,"date":"2019-03-11T05:00:10","date_gmt":"2019-03-11T05:00:10","guid":{"rendered":"http:\/\/esp16.epgpbooks.inflibnet.ac.in\/?post_type=chapter&#038;p=553"},"modified":"2019-04-25T07:38:46","modified_gmt":"2019-04-25T07:38:46","slug":"soil-ii-essential-macro-and-micro-elements-and-ion-exchange","status":"publish","type":"chapter","link":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/chapter\/soil-ii-essential-macro-and-micro-elements-and-ion-exchange\/","title":{"rendered":"Soil- II (Essential, Macro and Micro Elements and Ion Exchange)"},"content":{"raw":"<div><span style=\"float: right\"><a href=\"https:\/\/youtu.be\/Xt0ojPhzNq0\" target=\"_blank\" rel=\"noopener\"><img src=\"http:\/\/epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/2018\/11\/download.png\" alt=\"epgp books\" width=\"75px\" height=\"75px;\" \/><\/a>\r\n<\/span><\/div>\r\n&nbsp;\r\n\r\n<strong>Contents<\/strong>\r\n<p style=\"text-align: justify\">1) Fertility of soil<\/p>\r\n<p style=\"text-align: justify\">2) Essential elements<\/p>\r\n<p style=\"text-align: justify\">3) Macronutrients and their functions<\/p>\r\n<p style=\"text-align: justify\">4) Micronutrients and their functions<\/p>\r\n<p style=\"text-align: justify\">5) Cation Exchange capacity<\/p>\r\n<p style=\"text-align: justify\">6) Anion exchange capacity<\/p>\r\n<p style=\"text-align: justify\">7) Exchangeable sodium percentage<\/p>\r\n<p style=\"text-align: justify\">8) Significance of Soil Ion Exchange<\/p>\r\n<p style=\"text-align: justify\">9) Soil pH<\/p>\r\n<p style=\"text-align: justify\">10) Adjustment of soil acidity<\/p>\r\n11) Nitrogen cycle\r\n\r\n12) References\r\n\r\n&nbsp;\r\n\r\n<strong>Fertility of Soil<\/strong>\r\n<p style=\"text-align: justify\">Soil that produces abundant crops under the appropriate environmental conditions is coined the term \u201cfertile\u201d. Soil fertility reflects the soil- plant relationship <em>with reference to<\/em> plant nutrients available in soil. Understanding the principles of soil fertility is vital to efficient nutrient management, profitable crop protection and environmental protection.<\/p>\r\n<p style=\"text-align: justify\">By definition, soil fertility is defined as the innate capacity of soil to provide adequate amount of nutrients essential for plant growth during favorable conditions such as temperature, water and light, and the physical condition of soil while soil productivity is the economic concept that signifies the capability of soil to produce specified plants under well-defined and specified systems of management inputs and environmental conditions. It is a function of several factors rather than being a soil property alone.<\/p>\r\n&nbsp;\r\n\r\n<strong>Essential elements<\/strong>\r\n<p style=\"text-align: justify\">For an element to be called as essential, it needs to meet the following criteria-<\/p>\r\n<p style=\"text-align: justify\">The plant cannot complete its life cycle (seed to new seed) without it. If the element is specific in its physiological function in plants<\/p>\r\n<p style=\"text-align: justify\">If the malady that develops in plant can be remedied only by that element.<\/p>\r\n<p style=\"text-align: justify\">The element\u2019s function cannot be replaced by another element.<\/p>\r\n<p style=\"text-align: justify\">The element is directly involved in the plant\u2019s growth and reproduction.<\/p>\r\n&nbsp;\r\n<p style=\"text-align: justify\">Overall, 18 elements have been identified as essential for the growth of all plants. They are further classified not on their relative importance but on basis of their relative amounts into: <strong><em>Macronutrients<\/em><\/strong> (C, H, O, N, P, K, Ca, Mg, S) and <strong><em>Micronutrients<\/em><\/strong>(B, Cu, Fe, Mn, Zn, Mo, Cl, Co, Ni)<\/p>\r\n&nbsp;\r\n\r\n<strong>Macronutrients<\/strong>\r\n<p style=\"text-align: justify\">The elements occurring in ample levels in plant biomass and fluids are known as macronutrients. They are divided into three classes: Structural (C, H, O), Primary (N, P, K) and Secondary (Ca, Mg, S).<\/p>\r\n<strong>Table 1: Macro-elemental nutrient, their uptake form and their plant mobility<\/strong>\r\n<table style=\"border-collapse: collapse;width: 95.079%\" border=\"1\">\r\n<tbody>\r\n<tr>\r\n<td style=\"width: 8.85173%\"><\/td>\r\n<td style=\"width: 18.573%\"><strong>Nutrient<\/strong><\/td>\r\n<td style=\"width: 22.3633%\"><strong>Uptake form<\/strong><\/td>\r\n<td style=\"width: 18.9076%\"><strong>Mobility in Plant<\/strong><\/td>\r\n<td style=\"width: 26.3286%\"><strong>Mobility in Soil<\/strong><\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 8.85173%\"><strong>1.<\/strong><\/td>\r\n<td style=\"width: 18.573%\">Carbon<\/td>\r\n<td style=\"width: 22.3633%\">CO2,H2CO3<\/td>\r\n<td style=\"width: 18.9076%\"><\/td>\r\n<td style=\"width: 26.3286%\"><\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 8.85173%\"><strong>2<\/strong><\/td>\r\n<td style=\"width: 18.573%\">Hydrogen<\/td>\r\n<td style=\"width: 22.3633%\">H+, OH-, H2O<\/td>\r\n<td style=\"width: 18.9076%\"><\/td>\r\n<td style=\"width: 26.3286%\"><\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 8.85173%\"><strong>3<\/strong><\/td>\r\n<td style=\"width: 18.573%\">Oxygen<\/td>\r\n<td style=\"width: 22.3633%\">O2<\/td>\r\n<td style=\"width: 18.9076%\"><\/td>\r\n<td style=\"width: 26.3286%\"><\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 8.85173%\"><strong>4<\/strong><\/td>\r\n<td style=\"width: 18.573%\">Nitrogen<\/td>\r\n<td style=\"width: 22.3633%\">NO3-, NH4+<\/td>\r\n<td style=\"width: 18.9076%\">Mobile<\/td>\r\n<td style=\"width: 26.3286%\">Mobile as NO3-, immobile as NH4+<\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 8.85173%\"><strong>5<\/strong><\/td>\r\n<td style=\"width: 18.573%\">Phosphorous<\/td>\r\n<td style=\"width: 22.3633%\">HPO42-, H2PO4-<\/td>\r\n<td style=\"width: 18.9076%\">Somewhat mobile<\/td>\r\n<td style=\"width: 26.3286%\">Immobile<\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 8.85173%\"><strong>6<\/strong><\/td>\r\n<td style=\"width: 18.573%\">Potassium<\/td>\r\n<td style=\"width: 22.3633%\">K+<\/td>\r\n<td style=\"width: 18.9076%\">Very mobile<\/td>\r\n<td style=\"width: 26.3286%\">Somewhat mobile<\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 8.85173%\"><strong>7<\/strong><\/td>\r\n<td style=\"width: 18.573%\">Calcium<\/td>\r\n<td style=\"width: 22.3633%\">Ca2+<\/td>\r\n<td style=\"width: 18.9076%\">Immobile<\/td>\r\n<td style=\"width: 26.3286%\">Somewhat mobile<\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 8.85173%\"><strong>8<\/strong><\/td>\r\n<td style=\"width: 18.573%\">Magnesium<\/td>\r\n<td style=\"width: 22.3633%\">Mg2+<\/td>\r\n<td style=\"width: 18.9076%\">Somewhat mobile<\/td>\r\n<td style=\"width: 26.3286%\">Immobile<\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 8.85173%\"><strong>9<\/strong><\/td>\r\n<td style=\"width: 18.573%\">Sulphur<\/td>\r\n<td style=\"width: 22.3633%\">SO4-<\/td>\r\n<td style=\"width: 18.9076%\">Mobile<\/td>\r\n<td style=\"width: 26.3286%\">Mobile<\/td>\r\n<\/tr>\r\n<\/tbody>\r\n<\/table>\r\n&nbsp;\r\n\r\n<strong>Functions of Macronutrients<\/strong>\r\n\r\n&nbsp;\r\n<p style=\"text-align: justify\"><strong><em>(1) <\/em><\/strong>Carbon, Hydrogen, Oxygen- It is the foremost component of carbohydrates, proteins and fats (94% of dry weight of plants). They aid in oxidative breakdown of carbohydrates, proteins and fats during cellular respiration. They also provide energy for the growth and development of plants. They are also called structural nutrients.<\/p>\r\n<p style=\"text-align: justify\"><strong><em>(2) <\/em><\/strong>Nitrogen- It plays key role in, respiration and synthesis of proteins. It maintains fertility when bound to humus. It increases tillering and promotes vegetative growth of food crops. <em>Deficiency <\/em>leads to decrease in rate and degree of protein synthesis, development of chlorosis<\/p>\r\n<p style=\"text-align: justify\"><strong><em>\u00a0<\/em><\/strong><strong><em>(3) <\/em><\/strong>Phosphorus- It makes up for structural component of membrane systems. Provides resistance to diseases in plants and also influences cell division, root growth, fruit and seed development. <em>Deficiency <\/em>leads to restriction in root and shoot growth, shedding of leaves and delaying in flowering<\/p>\r\n<p style=\"text-align: justify\"><strong><em>\u00a0<\/em><\/strong><strong><em>(4) <\/em><\/strong>Potassium \u2013 It maintains water balance. It is an indispensable constituent of chlorophyll. It provides protection against fungal and bacterial diseases. <em>Deficiency<\/em> leads to development of chlorosis and drying back tips of shoots and reduced growth of shoots<\/p>\r\n<p style=\"text-align: justify\"><strong><em>\u00a0<\/em><\/strong><strong><em>(5) <\/em><\/strong>Calcium- It controls soil acidity. It is involved in root elongation and cell division. It also acts as a buffer in plant system. It improves intake of plant nutrient by correcting the pH of soil. <em>Deficiency <\/em>leads to wrinkled leaves, shorter roots, decrease in growth of plant.<\/p>\r\n<p style=\"text-align: justify\"><strong><em>\u00a0<\/em><\/strong><strong><em>(6) <\/em><\/strong>Magnesium- It is an important constituent of chlorophyll. It controls uptake of N and P from soil and also acts as a catalyst in activation of enzymes. <em>Deficiency<\/em> leads to premature defoliation<\/p>\r\n<p style=\"text-align: justify\"><strong><em>\u00a0<\/em><\/strong><strong><em>(7) <\/em><\/strong>Sulphur- It promotes module formation, root growth and seed formation. It increases oil content in oil bearing plants. It is an essential nutrient for cereals, sugars. <em>Deficiency<\/em> leads to brittle leaves and stems.<\/p>\r\n&nbsp;\r\n\r\n<strong>Micronutrients<\/strong>\r\n<ul>\r\n \t<li>These nutrients are required in lesser amounts as they are toxic at high levels<\/li>\r\n \t<li style=\"text-align: justify\">They stimulate plant growth and actively participate in photosynthesis.<\/li>\r\n \t<li>They show catalytic behavior in plant processes.<\/li>\r\n \t<li>Their deficiency hampers plant growth, photosynthetic rate reducing crop yield.<\/li>\r\n \t<li>Deficiency may cause shedding of flowers, poor seed setting and attack of diseases.<\/li>\r\n<\/ul>\r\n<strong>Table 2: Micro-elemental nutrient, their uptake form and their plant mobility<\/strong>\r\n<table style=\"border-collapse: collapse;width: 85.8574%;height: 239px\" border=\"1\">\r\n<tbody>\r\n<tr style=\"height: 43px\">\r\n<td style=\"width: 13.6392%;height: 43px\"><strong>Nutrient<\/strong><\/td>\r\n<td style=\"width: 15.6549%;height: 43px\"><strong>Uptake form<\/strong><\/td>\r\n<td style=\"width: 17.7826%;height: 43px\"><strong>Mobility in Plant<\/strong><\/td>\r\n<td style=\"width: 19.463%;height: 43px\"><strong>Mobility in Soil<\/strong><\/td>\r\n<td style=\"width: 19.2062%;height: 43px\"><strong>Typical\u00a0\u00a0 Range\u00a0\u00a0 of\u00a0Soil Content+<\/strong><\/td>\r\n<\/tr>\r\n<tr style=\"height: 28px\">\r\n<td style=\"width: 13.6392%;height: 28px\">Iron<\/td>\r\n<td style=\"width: 15.6549%;height: 28px\">Fe2+, Fe3+<\/td>\r\n<td style=\"width: 17.7826%;height: 28px\">Immobile<\/td>\r\n<td style=\"width: 19.463%;height: 28px\">Immobile<\/td>\r\n<td style=\"width: 19.2062%;height: 28px\">0.01-21%<\/td>\r\n<\/tr>\r\n<tr style=\"height: 28px\">\r\n<td style=\"width: 13.6392%;height: 28px\">Boron<\/td>\r\n<td style=\"width: 15.6549%;height: 28px\">H3BO3, BO3<\/td>\r\n<td style=\"width: 17.7826%;height: 28px\">Immobile<\/td>\r\n<td style=\"width: 19.463%;height: 28px\">Very mobile<\/td>\r\n<td style=\"width: 19.2062%;height: 28px\">0.9-1000<\/td>\r\n<\/tr>\r\n<tr style=\"height: 28px\">\r\n<td style=\"width: 13.6392%;height: 28px\">Copper<\/td>\r\n<td style=\"width: 15.6549%;height: 28px\">Cu2+<\/td>\r\n<td style=\"width: 17.7826%;height: 28px\">Immobile<\/td>\r\n<td style=\"width: 19.463%;height: 28px\">Immobile<\/td>\r\n<td style=\"width: 19.2062%;height: 28px\">2.5-60<\/td>\r\n<\/tr>\r\n<tr style=\"height: 28px\">\r\n<td style=\"width: 13.6392%;height: 28px\">Chlorine<\/td>\r\n<td style=\"width: 15.6549%;height: 28px\">Cl-<\/td>\r\n<td style=\"width: 17.7826%;height: 28px\">Mobile<\/td>\r\n<td style=\"width: 19.463%;height: 28px\">Mobile<\/td>\r\n<td style=\"width: 19.2062%;height: 28px\">18-806<\/td>\r\n<\/tr>\r\n<tr style=\"height: 28px\">\r\n<td style=\"width: 13.6392%;height: 28px\">Manganese<\/td>\r\n<td style=\"width: 15.6549%;height: 28px\">Mn2+<\/td>\r\n<td style=\"width: 17.7826%;height: 28px\">Immobile<\/td>\r\n<td style=\"width: 19.463%;height: 28px\">Mobile<\/td>\r\n<td style=\"width: 19.2062%;height: 28px\">&lt;1-18300<\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 13.6392%\">Molybdenum<\/td>\r\n<td style=\"width: 15.6549%\">MoO4-<\/td>\r\n<td style=\"width: 17.7826%\">Immobile<\/td>\r\n<td style=\"width: 19.463%\">Somewhat<\/td>\r\n<td style=\"width: 19.2062%\">0.07-5<\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 13.6392%\">Zinc<\/td>\r\n<td style=\"width: 15.6549%\">Zn2+<\/td>\r\n<td style=\"width: 17.7826%\">Immobile<\/td>\r\n<td style=\"width: 19.463%\">Immobile<\/td>\r\n<td style=\"width: 19.2062%\">1.5-2000<\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 13.6392%\">Cobalt<\/td>\r\n<td style=\"width: 15.6549%\">Co2+<\/td>\r\n<td style=\"width: 17.7826%\">Immobile<\/td>\r\n<td style=\"width: 19.463%\">Somewhat\u00a0immobile<\/td>\r\n<td style=\"width: 19.2062%\">0.3-200<\/td>\r\n<\/tr>\r\n<tr>\r\n<td style=\"width: 13.6392%\">Nickel<\/td>\r\n<td style=\"width: 15.6549%\">Ni2+<\/td>\r\n<td style=\"width: 17.7826%\">Mobile<\/td>\r\n<td style=\"width: 19.463%\">Somewhat\u00a0mobile<\/td>\r\n<td style=\"width: 19.2062%\">0.1-1523<\/td>\r\n<\/tr>\r\n<\/tbody>\r\n<\/table>\r\n+Unit of measurement is mg\/kg except where % is used\r\n\r\n&nbsp;\r\n\r\n<strong>Functions of Micronutrients<\/strong>\r\n<p style=\"text-align: justify\">(1) Iron- Aids in chlorophyll formation<\/p>\r\n<p style=\"text-align: justify\">(2) Boron- It regulates nutrients, production of sugar and carbohydrates and also is essential for fruit and seed.<\/p>\r\n<p style=\"text-align: justify\">(3) Copper \u2013 It is important for the proper reproductive growth. It abets root metabolism and helps in the consumption of proteins<\/p>\r\n<p style=\"text-align: justify\">(4) Manganese \u2013 It functions with enzyme systems involved in breakdown of carbohydrates and nitrogen metabolism. It regulates the intake and state of oxidation of various elements.<\/p>\r\n<p style=\"text-align: justify\">(5) Chloride- It aids plant carbohydrate metabolism and stimulates enzymatic activity<\/p>\r\n<p style=\"text-align: justify\">(6) Molybdenum- It helps in the use of nitrogen and in nitrogen fixation as it is constituent of nitrate reductase and nitrogenase enzyme<\/p>\r\n<p style=\"text-align: justify\">(7) Zinc- It contributes in mechanism for the transformation of carbohydrates and consumption of sugars and also constitutes a part of enzyme systems that regulate plant growth.<\/p>\r\n<p style=\"text-align: justify\">(8) Cobalt- It plays an indispensable role in Vitamin B12 production and thus assists in the process of nitrogen-fixation thus affecting plant growth and metabolism<\/p>\r\n<p style=\"text-align: justify\">(9) Nickel- It prevents urea accumulation to toxic levels and leaflet tip necrosis. It is essential for the mobilization of stored seed-nitrogen.<\/p>\r\n&nbsp;\r\n\r\n<strong>Cation Exchange Capacity (CEC)<\/strong>\r\n<p style=\"text-align: justify\">It refers to the capacity of soil to exchange cations to enhance the availability of essential trace metals to plants. Mathematically it is defined as number of <em>meq<\/em> of monovalent cations that can be exchanged per 100g of soil. The value of CEC varies with soil conditions and pH.CEC increases with presence of negatively charged sites on minerals. Humus has high CEC (300-400 meq\/100g) while that of organic matter soil (10-30 meq\/100g)<\/p>\r\n&nbsp;\r\n\r\n<strong>Anion Exchange Capacity (AEC)<\/strong>\r\n<p style=\"text-align: justify\">It is defined as the measurement of the positive charges in soils being affected by the amount of negative charges which a soil can absorb. The value of AEC is directly proportional to change in pH while in case of CEC, reverse trend is seen. The relative strength of adsorption of cations and anions can be illustrated by Lyotrophilic series as follows:<\/p>\r\n<img class=\"aligncenter size-full wp-image-554\" src=\"http:\/\/esp16.epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/sites\/161\/2019\/03\/1-368.png\" alt=\"\" width=\"337\" height=\"65\" \/><strong style=\"text-align: initial;font-size: 1em\">Exchangeable sodium percentage (ESP)<\/strong>\r\n<div>\r\n<p style=\"text-align: justify\">It reflects the alkalinity of soil. If ESP is greater than 15 then soil gets dispersed causing sodium toxicity. It also becomes impervious to water and hence unfavorable for plant growth. Moreover, the availability of plant nutrients is reduced and crop growth is affected. The exchangeable sodium reacts with carbon dioxide forming sodium carbonate which on accumulation renders soil alkaline and ultimately infertile.<\/p>\r\n\r\n<\/div>\r\n<div>\r\n\r\n\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0Soil-Na + H2O\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0Soil-H + NaOH\r\n\r\n2NaOH + CO2\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0Na2CO3 +H2O\r\n\r\n<\/div>\r\n&nbsp;\r\n<div>\r\n<p style=\"text-align: justify\"><strong>Significance of Soil Ion Exchange<\/strong><\/p>\r\n\r\n<ul style=\"text-align: justify\">\r\n \t<li>Base saturation of soil is an indicator of the degree of weathering.<\/li>\r\n \t<li>CEC, supported by the data on clay content is useful for soil management purposes.<\/li>\r\n \t<li>CEC is an indicator of the nutrient storage capacity of soil.<\/li>\r\n \t<li>The information on exchangeable cations is used in soil classification.<\/li>\r\n<\/ul>\r\n<p style=\"text-align: justify\"><strong>Soil pH<\/strong><\/p>\r\n<p style=\"text-align: justify\">It is a measure of soil acidity or alkalinity. pH is called a \u2018master\u2019 variable because:<\/p>\r\n\r\n<ul style=\"text-align: justify\">\r\n \t<li>\u00fc affects chemical, physical, and biological properties of soils<\/li>\r\n \t<li>\u00fc Nutrient availability (optimum pH for most crops is 5.5 - 7)<\/li>\r\n \t<li>\u00fc Metal toxicity and solubility e.g., Al toxicity at pH &lt;5.5<\/li>\r\n \t<li>\u00fc Microbial activity (especially important in the N cycle)pH= 6-8highest N contentpH= 6-7.5\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 high P contentpH&lt;6 (acidic soil) Formation of insoluble compounds of P with Fe and Al pH&gt;6 (alkaline soil) Formation of insoluble compounds of P with Ca<\/li>\r\n<\/ul>\r\n<p style=\"text-align: justify\"><strong>Alteration of pH<\/strong><\/p>\r\n&nbsp;\r\n<p style=\"text-align: justify\">pH can be reduced by<\/p>\r\n\r\n<ul style=\"text-align: justify\">\r\n \t<li>Addition of iron or aluminium sulfate, S (forms sulphuric acid)<\/li>\r\n \t<li>Addition of urea, ammonium (nitrate, sulphate and phosphate) and mono potassium phosphate fertilizers<\/li>\r\n \t<li>Addition of pine needles, sawdust and acid peat.<\/li>\r\n \t<li>decomposition of organic matter in the form of plant litter, compost and manure<\/li>\r\n<\/ul>\r\n<p style=\"text-align: justify\">pH can be increased by<\/p>\r\n\r\n<ul style=\"text-align: justify\">\r\n \t<li>Addition of lime (CaCO3 or MgCO3)<\/li>\r\n \t<li>Addition of wood and oyster shells<\/li>\r\n \t<li>Addition of calcium silicate (removes free hydrogen ions which in turn leads to neutralization of active acidity)<\/li>\r\n<\/ul>\r\n<p style=\"text-align: justify\"><strong>Adjustment of Soil Acidity<\/strong><\/p>\r\n\r\n<ul>\r\n \t<li style=\"text-align: justify\">If the soil becomes too acidic, it can be refurbished by liming<\/li>\r\n \t<li style=\"text-align: justify\">If soil becomes too alkaline (in areas receiving scanty rainfall), it can be treated with aluminum or iron sulfate, releases acid on hydrolysis.<\/li>\r\n<\/ul>\r\n<img class=\"aligncenter size-full wp-image-555\" src=\"http:\/\/esp16.epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/sites\/161\/2019\/03\/1-369.png\" alt=\"\" width=\"422\" height=\"32\" \/>\r\n<ul>\r\n \t<li>Sulphur is added to soils is oxidized by bacterially mediated reactions to sulphuric acid<\/li>\r\n<\/ul>\r\n<img class=\"aligncenter size-full wp-image-556\" src=\"http:\/\/esp16.epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/sites\/161\/2019\/03\/1-370.png\" alt=\"\" width=\"285\" height=\"56\" \/><strong>Nitrogen cycle<\/strong>\r\n<p style=\"text-align: justify\">Molecular nitrogen from air is fixed by soil organisms. Nitrogen enters into the bodies of soil organism and organic substances (humus) in soil through the process of decomposition and is further recycled through plants and animals.<\/p>\r\n<img class=\"aligncenter size-full wp-image-557\" src=\"http:\/\/esp16.epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/sites\/161\/2019\/03\/1-371.png\" alt=\"\" width=\"532\" height=\"298\" \/>\r\n\r\n<strong>\u00a0 \u00a0Figure 1: Nitrogen cycle<\/strong>\r\n\r\n&nbsp;\r\n<p style=\"text-align: justify\"><em>Ammonification <\/em>is a process in which nitrogen containing organic molecules present in soil is converted into ammonium compounds. The amount of accumulation of ammonium varies with organism, soil and environment.<\/p>\r\n<p style=\"text-align: justify\"><em>Nitrification <\/em>is a process in which ammonium or other reduced forms of nitrogen are oxidized to nitrite and nitrate with the help of nitrifying agents including <em>nitrosomonas<\/em> and <em>nitrobacter.<\/em> The nitrate formed is utilized by crops and soil organisms for nutrition purpose.<\/p>\r\n<p style=\"text-align: justify\"><em>Denitrification <\/em>is a process of conversion of nitrite and nitrate into molecular nitrogen. It is caused by <em>Pseudomonas, Bacillus<\/em>,<em>Paracoccus. The a<\/em>naerobic condition of soil is conducive to denitrification<\/p>\r\n<p style=\"text-align: justify\">Nitrogen cycle leads to formation of microbial cells and organic matter in soil and its intermediate by-products leads to formation of humus in soil.<\/p>\r\n\r\n<\/div>\r\n<table>\r\n<tbody>\r\n<tr>\r\n<td><strong>you can view video on Soil- II (Essential, Macro and Micro Elements and Ion Exchange)<\/strong><\/td>\r\n<td><a href=\"https:\/\/youtu.be\/Xt0ojPhzNq0\" target=\"_blank\" rel=\"noopener\"><img class=\"alignnone wp-image-120\" src=\"http:\/\/epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/2018\/11\/download.png\" alt=\"\" width=\"36\" height=\"36\" \/><\/a><\/td>\r\n<\/tr>\r\n<\/tbody>\r\n<\/table>\r\n<div class=\"textbox exercises\">\r\n<h3>References:<\/h3>\r\n<ul>\r\n \t<li>Wild, A. Russell\u2019s \u201cSoil conditions and Plant growth\u201d, (11thedn) Longman Scientific and Technical, Harlow, Essex, UK, 1998.<\/li>\r\n \t<li>Epstein, E. \u201cMineral Nutrition of Plants: Principles and Perspectives\u201d, John Wiley &amp; Sons, Inc. New York USA, 1972.<\/li>\r\n \t<li>Marschner, H. \u201cMineral Nutrition of higher plants\u201d, Academic Press, London, U.K., 1995<\/li>\r\n \t<li>\u00a0Alexander, M. \u201cIntroduction to Soil Microbiology\u201d, 2ndedn, John Wiley &amp; Sons, New York, 1972 (Indian reprint, 1983, Wiley Eastern Limited, New Delhi).<\/li>\r\n \t<li>Biswas T. D. and Mukherjee S. K. \u201cTextbook of Soil Science\u201d, Tata Mc Graw- Hill Publishing Company Ltd, New Delhi, 1994.<\/li>\r\n \t<li>Chesworth, W. Ed., \u201cEncyclopedia of Soil Science\u201d, Springer, Dordrecht, The Netherlands, 2008.<\/li>\r\n \t<li>Manahan, S.E. \u201cEnvironmental Chemistry\u201d, CRC Press, Taylor &amp; Francis, New York, 2010.<\/li>\r\n \t<li><a href=\"http:\/\/www.marietta.edu\/~biol\/102\/ecosystem.html\">http:\/\/www.marietta.edu\/~biol\/102\/ecosystem.html<\/a><\/li>\r\n \t<li><a href=\"http:\/\/soil.hostweb.org.uk\/\">http:\/\/soil.hostweb.org.uk\/<\/a><\/li>\r\n \t<li><a href=\"http:\/\/landresources.montana.edu\/NM\/Modules\/mt44492.pdf\">http:\/\/landresources.montana.edu\/NM\/Modules\/mt44492.pdf<\/a><\/li>\r\n<\/ul>\r\n<\/div>\r\n<div><\/div>","rendered":"<div><span style=\"float: right\"><a href=\"https:\/\/youtu.be\/Xt0ojPhzNq0\" target=\"_blank\" rel=\"noopener\"><img decoding=\"async\" src=\"http:\/\/epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/2018\/11\/download.png\" alt=\"epgp books\" width=\"75px\" height=\"75px;\" \/><\/a><br \/>\n<\/span><\/div>\n<p>&nbsp;<\/p>\n<p><strong>Contents<\/strong><\/p>\n<p style=\"text-align: justify\">1) Fertility of soil<\/p>\n<p style=\"text-align: justify\">2) Essential elements<\/p>\n<p style=\"text-align: justify\">3) Macronutrients and their functions<\/p>\n<p style=\"text-align: justify\">4) Micronutrients and their functions<\/p>\n<p style=\"text-align: justify\">5) Cation Exchange capacity<\/p>\n<p style=\"text-align: justify\">6) Anion exchange capacity<\/p>\n<p style=\"text-align: justify\">7) Exchangeable sodium percentage<\/p>\n<p style=\"text-align: justify\">8) Significance of Soil Ion Exchange<\/p>\n<p style=\"text-align: justify\">9) Soil pH<\/p>\n<p style=\"text-align: justify\">10) Adjustment of soil acidity<\/p>\n<p>11) Nitrogen cycle<\/p>\n<p>12) References<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Fertility of Soil<\/strong><\/p>\n<p style=\"text-align: justify\">Soil that produces abundant crops under the appropriate environmental conditions is coined the term \u201cfertile\u201d. Soil fertility reflects the soil- plant relationship <em>with reference to<\/em> plant nutrients available in soil. Understanding the principles of soil fertility is vital to efficient nutrient management, profitable crop protection and environmental protection.<\/p>\n<p style=\"text-align: justify\">By definition, soil fertility is defined as the innate capacity of soil to provide adequate amount of nutrients essential for plant growth during favorable conditions such as temperature, water and light, and the physical condition of soil while soil productivity is the economic concept that signifies the capability of soil to produce specified plants under well-defined and specified systems of management inputs and environmental conditions. It is a function of several factors rather than being a soil property alone.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Essential elements<\/strong><\/p>\n<p style=\"text-align: justify\">For an element to be called as essential, it needs to meet the following criteria-<\/p>\n<p style=\"text-align: justify\">The plant cannot complete its life cycle (seed to new seed) without it. If the element is specific in its physiological function in plants<\/p>\n<p style=\"text-align: justify\">If the malady that develops in plant can be remedied only by that element.<\/p>\n<p style=\"text-align: justify\">The element\u2019s function cannot be replaced by another element.<\/p>\n<p style=\"text-align: justify\">The element is directly involved in the plant\u2019s growth and reproduction.<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: justify\">Overall, 18 elements have been identified as essential for the growth of all plants. They are further classified not on their relative importance but on basis of their relative amounts into: <strong><em>Macronutrients<\/em><\/strong> (C, H, O, N, P, K, Ca, Mg, S) and <strong><em>Micronutrients<\/em><\/strong>(B, Cu, Fe, Mn, Zn, Mo, Cl, Co, Ni)<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Macronutrients<\/strong><\/p>\n<p style=\"text-align: justify\">The elements occurring in ample levels in plant biomass and fluids are known as macronutrients. They are divided into three classes: Structural (C, H, O), Primary (N, P, K) and Secondary (Ca, Mg, S).<\/p>\n<p><strong>Table 1: Macro-elemental nutrient, their uptake form and their plant mobility<\/strong><\/p>\n<table style=\"border-collapse: collapse;width: 95.079%\">\n<tbody>\n<tr>\n<td style=\"width: 8.85173%\"><\/td>\n<td style=\"width: 18.573%\"><strong>Nutrient<\/strong><\/td>\n<td style=\"width: 22.3633%\"><strong>Uptake form<\/strong><\/td>\n<td style=\"width: 18.9076%\"><strong>Mobility in Plant<\/strong><\/td>\n<td style=\"width: 26.3286%\"><strong>Mobility in Soil<\/strong><\/td>\n<\/tr>\n<tr>\n<td style=\"width: 8.85173%\"><strong>1.<\/strong><\/td>\n<td style=\"width: 18.573%\">Carbon<\/td>\n<td style=\"width: 22.3633%\">CO2,H2CO3<\/td>\n<td style=\"width: 18.9076%\"><\/td>\n<td style=\"width: 26.3286%\"><\/td>\n<\/tr>\n<tr>\n<td style=\"width: 8.85173%\"><strong>2<\/strong><\/td>\n<td style=\"width: 18.573%\">Hydrogen<\/td>\n<td style=\"width: 22.3633%\">H+, OH-, H2O<\/td>\n<td style=\"width: 18.9076%\"><\/td>\n<td style=\"width: 26.3286%\"><\/td>\n<\/tr>\n<tr>\n<td style=\"width: 8.85173%\"><strong>3<\/strong><\/td>\n<td style=\"width: 18.573%\">Oxygen<\/td>\n<td style=\"width: 22.3633%\">O2<\/td>\n<td style=\"width: 18.9076%\"><\/td>\n<td style=\"width: 26.3286%\"><\/td>\n<\/tr>\n<tr>\n<td style=\"width: 8.85173%\"><strong>4<\/strong><\/td>\n<td style=\"width: 18.573%\">Nitrogen<\/td>\n<td style=\"width: 22.3633%\">NO3-, NH4+<\/td>\n<td style=\"width: 18.9076%\">Mobile<\/td>\n<td style=\"width: 26.3286%\">Mobile as NO3-, immobile as NH4+<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 8.85173%\"><strong>5<\/strong><\/td>\n<td style=\"width: 18.573%\">Phosphorous<\/td>\n<td style=\"width: 22.3633%\">HPO42-, H2PO4-<\/td>\n<td style=\"width: 18.9076%\">Somewhat mobile<\/td>\n<td style=\"width: 26.3286%\">Immobile<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 8.85173%\"><strong>6<\/strong><\/td>\n<td style=\"width: 18.573%\">Potassium<\/td>\n<td style=\"width: 22.3633%\">K+<\/td>\n<td style=\"width: 18.9076%\">Very mobile<\/td>\n<td style=\"width: 26.3286%\">Somewhat mobile<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 8.85173%\"><strong>7<\/strong><\/td>\n<td style=\"width: 18.573%\">Calcium<\/td>\n<td style=\"width: 22.3633%\">Ca2+<\/td>\n<td style=\"width: 18.9076%\">Immobile<\/td>\n<td style=\"width: 26.3286%\">Somewhat mobile<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 8.85173%\"><strong>8<\/strong><\/td>\n<td style=\"width: 18.573%\">Magnesium<\/td>\n<td style=\"width: 22.3633%\">Mg2+<\/td>\n<td style=\"width: 18.9076%\">Somewhat mobile<\/td>\n<td style=\"width: 26.3286%\">Immobile<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 8.85173%\"><strong>9<\/strong><\/td>\n<td style=\"width: 18.573%\">Sulphur<\/td>\n<td style=\"width: 22.3633%\">SO4-<\/td>\n<td style=\"width: 18.9076%\">Mobile<\/td>\n<td style=\"width: 26.3286%\">Mobile<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>&nbsp;<\/p>\n<p><strong>Functions of Macronutrients<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: justify\"><strong><em>(1) <\/em><\/strong>Carbon, Hydrogen, Oxygen- It is the foremost component of carbohydrates, proteins and fats (94% of dry weight of plants). They aid in oxidative breakdown of carbohydrates, proteins and fats during cellular respiration. They also provide energy for the growth and development of plants. They are also called structural nutrients.<\/p>\n<p style=\"text-align: justify\"><strong><em>(2) <\/em><\/strong>Nitrogen- It plays key role in, respiration and synthesis of proteins. It maintains fertility when bound to humus. It increases tillering and promotes vegetative growth of food crops. <em>Deficiency <\/em>leads to decrease in rate and degree of protein synthesis, development of chlorosis<\/p>\n<p style=\"text-align: justify\"><strong><em>\u00a0<\/em><\/strong><strong><em>(3) <\/em><\/strong>Phosphorus- It makes up for structural component of membrane systems. Provides resistance to diseases in plants and also influences cell division, root growth, fruit and seed development. <em>Deficiency <\/em>leads to restriction in root and shoot growth, shedding of leaves and delaying in flowering<\/p>\n<p style=\"text-align: justify\"><strong><em>\u00a0<\/em><\/strong><strong><em>(4) <\/em><\/strong>Potassium \u2013 It maintains water balance. It is an indispensable constituent of chlorophyll. It provides protection against fungal and bacterial diseases. <em>Deficiency<\/em> leads to development of chlorosis and drying back tips of shoots and reduced growth of shoots<\/p>\n<p style=\"text-align: justify\"><strong><em>\u00a0<\/em><\/strong><strong><em>(5) <\/em><\/strong>Calcium- It controls soil acidity. It is involved in root elongation and cell division. It also acts as a buffer in plant system. It improves intake of plant nutrient by correcting the pH of soil. <em>Deficiency <\/em>leads to wrinkled leaves, shorter roots, decrease in growth of plant.<\/p>\n<p style=\"text-align: justify\"><strong><em>\u00a0<\/em><\/strong><strong><em>(6) <\/em><\/strong>Magnesium- It is an important constituent of chlorophyll. It controls uptake of N and P from soil and also acts as a catalyst in activation of enzymes. <em>Deficiency<\/em> leads to premature defoliation<\/p>\n<p style=\"text-align: justify\"><strong><em>\u00a0<\/em><\/strong><strong><em>(7) <\/em><\/strong>Sulphur- It promotes module formation, root growth and seed formation. It increases oil content in oil bearing plants. It is an essential nutrient for cereals, sugars. <em>Deficiency<\/em> leads to brittle leaves and stems.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Micronutrients<\/strong><\/p>\n<ul>\n<li>These nutrients are required in lesser amounts as they are toxic at high levels<\/li>\n<li style=\"text-align: justify\">They stimulate plant growth and actively participate in photosynthesis.<\/li>\n<li>They show catalytic behavior in plant processes.<\/li>\n<li>Their deficiency hampers plant growth, photosynthetic rate reducing crop yield.<\/li>\n<li>Deficiency may cause shedding of flowers, poor seed setting and attack of diseases.<\/li>\n<\/ul>\n<p><strong>Table 2: Micro-elemental nutrient, their uptake form and their plant mobility<\/strong><\/p>\n<table style=\"border-collapse: collapse;width: 85.8574%;height: 239px\">\n<tbody>\n<tr style=\"height: 43px\">\n<td style=\"width: 13.6392%;height: 43px\"><strong>Nutrient<\/strong><\/td>\n<td style=\"width: 15.6549%;height: 43px\"><strong>Uptake form<\/strong><\/td>\n<td style=\"width: 17.7826%;height: 43px\"><strong>Mobility in Plant<\/strong><\/td>\n<td style=\"width: 19.463%;height: 43px\"><strong>Mobility in Soil<\/strong><\/td>\n<td style=\"width: 19.2062%;height: 43px\"><strong>Typical\u00a0\u00a0 Range\u00a0\u00a0 of\u00a0Soil Content+<\/strong><\/td>\n<\/tr>\n<tr style=\"height: 28px\">\n<td style=\"width: 13.6392%;height: 28px\">Iron<\/td>\n<td style=\"width: 15.6549%;height: 28px\">Fe2+, Fe3+<\/td>\n<td style=\"width: 17.7826%;height: 28px\">Immobile<\/td>\n<td style=\"width: 19.463%;height: 28px\">Immobile<\/td>\n<td style=\"width: 19.2062%;height: 28px\">0.01-21%<\/td>\n<\/tr>\n<tr style=\"height: 28px\">\n<td style=\"width: 13.6392%;height: 28px\">Boron<\/td>\n<td style=\"width: 15.6549%;height: 28px\">H3BO3, BO3<\/td>\n<td style=\"width: 17.7826%;height: 28px\">Immobile<\/td>\n<td style=\"width: 19.463%;height: 28px\">Very mobile<\/td>\n<td style=\"width: 19.2062%;height: 28px\">0.9-1000<\/td>\n<\/tr>\n<tr style=\"height: 28px\">\n<td style=\"width: 13.6392%;height: 28px\">Copper<\/td>\n<td style=\"width: 15.6549%;height: 28px\">Cu2+<\/td>\n<td style=\"width: 17.7826%;height: 28px\">Immobile<\/td>\n<td style=\"width: 19.463%;height: 28px\">Immobile<\/td>\n<td style=\"width: 19.2062%;height: 28px\">2.5-60<\/td>\n<\/tr>\n<tr style=\"height: 28px\">\n<td style=\"width: 13.6392%;height: 28px\">Chlorine<\/td>\n<td style=\"width: 15.6549%;height: 28px\">Cl-<\/td>\n<td style=\"width: 17.7826%;height: 28px\">Mobile<\/td>\n<td style=\"width: 19.463%;height: 28px\">Mobile<\/td>\n<td style=\"width: 19.2062%;height: 28px\">18-806<\/td>\n<\/tr>\n<tr style=\"height: 28px\">\n<td style=\"width: 13.6392%;height: 28px\">Manganese<\/td>\n<td style=\"width: 15.6549%;height: 28px\">Mn2+<\/td>\n<td style=\"width: 17.7826%;height: 28px\">Immobile<\/td>\n<td style=\"width: 19.463%;height: 28px\">Mobile<\/td>\n<td style=\"width: 19.2062%;height: 28px\">&lt;1-18300<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 13.6392%\">Molybdenum<\/td>\n<td style=\"width: 15.6549%\">MoO4-<\/td>\n<td style=\"width: 17.7826%\">Immobile<\/td>\n<td style=\"width: 19.463%\">Somewhat<\/td>\n<td style=\"width: 19.2062%\">0.07-5<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 13.6392%\">Zinc<\/td>\n<td style=\"width: 15.6549%\">Zn2+<\/td>\n<td style=\"width: 17.7826%\">Immobile<\/td>\n<td style=\"width: 19.463%\">Immobile<\/td>\n<td style=\"width: 19.2062%\">1.5-2000<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 13.6392%\">Cobalt<\/td>\n<td style=\"width: 15.6549%\">Co2+<\/td>\n<td style=\"width: 17.7826%\">Immobile<\/td>\n<td style=\"width: 19.463%\">Somewhat\u00a0immobile<\/td>\n<td style=\"width: 19.2062%\">0.3-200<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 13.6392%\">Nickel<\/td>\n<td style=\"width: 15.6549%\">Ni2+<\/td>\n<td style=\"width: 17.7826%\">Mobile<\/td>\n<td style=\"width: 19.463%\">Somewhat\u00a0mobile<\/td>\n<td style=\"width: 19.2062%\">0.1-1523<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>+Unit of measurement is mg\/kg except where % is used<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Functions of Micronutrients<\/strong><\/p>\n<p style=\"text-align: justify\">(1) Iron- Aids in chlorophyll formation<\/p>\n<p style=\"text-align: justify\">(2) Boron- It regulates nutrients, production of sugar and carbohydrates and also is essential for fruit and seed.<\/p>\n<p style=\"text-align: justify\">(3) Copper \u2013 It is important for the proper reproductive growth. It abets root metabolism and helps in the consumption of proteins<\/p>\n<p style=\"text-align: justify\">(4) Manganese \u2013 It functions with enzyme systems involved in breakdown of carbohydrates and nitrogen metabolism. It regulates the intake and state of oxidation of various elements.<\/p>\n<p style=\"text-align: justify\">(5) Chloride- It aids plant carbohydrate metabolism and stimulates enzymatic activity<\/p>\n<p style=\"text-align: justify\">(6) Molybdenum- It helps in the use of nitrogen and in nitrogen fixation as it is constituent of nitrate reductase and nitrogenase enzyme<\/p>\n<p style=\"text-align: justify\">(7) Zinc- It contributes in mechanism for the transformation of carbohydrates and consumption of sugars and also constitutes a part of enzyme systems that regulate plant growth.<\/p>\n<p style=\"text-align: justify\">(8) Cobalt- It plays an indispensable role in Vitamin B12 production and thus assists in the process of nitrogen-fixation thus affecting plant growth and metabolism<\/p>\n<p style=\"text-align: justify\">(9) Nickel- It prevents urea accumulation to toxic levels and leaflet tip necrosis. It is essential for the mobilization of stored seed-nitrogen.<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Cation Exchange Capacity (CEC)<\/strong><\/p>\n<p style=\"text-align: justify\">It refers to the capacity of soil to exchange cations to enhance the availability of essential trace metals to plants. Mathematically it is defined as number of <em>meq<\/em> of monovalent cations that can be exchanged per 100g of soil. The value of CEC varies with soil conditions and pH.CEC increases with presence of negatively charged sites on minerals. Humus has high CEC (300-400 meq\/100g) while that of organic matter soil (10-30 meq\/100g)<\/p>\n<p>&nbsp;<\/p>\n<p><strong>Anion Exchange Capacity (AEC)<\/strong><\/p>\n<p style=\"text-align: justify\">It is defined as the measurement of the positive charges in soils being affected by the amount of negative charges which a soil can absorb. The value of AEC is directly proportional to change in pH while in case of CEC, reverse trend is seen. The relative strength of adsorption of cations and anions can be illustrated by Lyotrophilic series as follows:<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-554\" src=\"http:\/\/esp16.epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/sites\/161\/2019\/03\/1-368.png\" alt=\"\" width=\"337\" height=\"65\" srcset=\"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-368.png 337w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-368-300x58.png 300w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-368-65x13.png 65w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-368-225x43.png 225w\" sizes=\"auto, (max-width: 337px) 100vw, 337px\" \/><strong style=\"text-align: initial;font-size: 1em\">Exchangeable sodium percentage (ESP)<\/strong><\/p>\n<div>\n<p style=\"text-align: justify\">It reflects the alkalinity of soil. If ESP is greater than 15 then soil gets dispersed causing sodium toxicity. It also becomes impervious to water and hence unfavorable for plant growth. Moreover, the availability of plant nutrients is reduced and crop growth is affected. The exchangeable sodium reacts with carbon dioxide forming sodium carbonate which on accumulation renders soil alkaline and ultimately infertile.<\/p>\n<\/div>\n<div>\n<p>\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0Soil-Na + H2O\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0Soil-H + NaOH<\/p>\n<p>2NaOH + CO2\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0Na2CO3 +H2O<\/p>\n<\/div>\n<p>&nbsp;<\/p>\n<div>\n<p style=\"text-align: justify\"><strong>Significance of Soil Ion Exchange<\/strong><\/p>\n<ul style=\"text-align: justify\">\n<li>Base saturation of soil is an indicator of the degree of weathering.<\/li>\n<li>CEC, supported by the data on clay content is useful for soil management purposes.<\/li>\n<li>CEC is an indicator of the nutrient storage capacity of soil.<\/li>\n<li>The information on exchangeable cations is used in soil classification.<\/li>\n<\/ul>\n<p style=\"text-align: justify\"><strong>Soil pH<\/strong><\/p>\n<p style=\"text-align: justify\">It is a measure of soil acidity or alkalinity. pH is called a \u2018master\u2019 variable because:<\/p>\n<ul style=\"text-align: justify\">\n<li>\u00fc affects chemical, physical, and biological properties of soils<\/li>\n<li>\u00fc Nutrient availability (optimum pH for most crops is 5.5 &#8211; 7)<\/li>\n<li>\u00fc Metal toxicity and solubility e.g., Al toxicity at pH &lt;5.5<\/li>\n<li>\u00fc Microbial activity (especially important in the N cycle)pH= 6-8highest N contentpH= 6-7.5\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 high P contentpH&lt;6 (acidic soil) Formation of insoluble compounds of P with Fe and Al pH&gt;6 (alkaline soil) Formation of insoluble compounds of P with Ca<\/li>\n<\/ul>\n<p style=\"text-align: justify\"><strong>Alteration of pH<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: justify\">pH can be reduced by<\/p>\n<ul style=\"text-align: justify\">\n<li>Addition of iron or aluminium sulfate, S (forms sulphuric acid)<\/li>\n<li>Addition of urea, ammonium (nitrate, sulphate and phosphate) and mono potassium phosphate fertilizers<\/li>\n<li>Addition of pine needles, sawdust and acid peat.<\/li>\n<li>decomposition of organic matter in the form of plant litter, compost and manure<\/li>\n<\/ul>\n<p style=\"text-align: justify\">pH can be increased by<\/p>\n<ul style=\"text-align: justify\">\n<li>Addition of lime (CaCO3 or MgCO3)<\/li>\n<li>Addition of wood and oyster shells<\/li>\n<li>Addition of calcium silicate (removes free hydrogen ions which in turn leads to neutralization of active acidity)<\/li>\n<\/ul>\n<p style=\"text-align: justify\"><strong>Adjustment of Soil Acidity<\/strong><\/p>\n<ul>\n<li style=\"text-align: justify\">If the soil becomes too acidic, it can be refurbished by liming<\/li>\n<li style=\"text-align: justify\">If soil becomes too alkaline (in areas receiving scanty rainfall), it can be treated with aluminum or iron sulfate, releases acid on hydrolysis.<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-555\" src=\"http:\/\/esp16.epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/sites\/161\/2019\/03\/1-369.png\" alt=\"\" width=\"422\" height=\"32\" srcset=\"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-369.png 422w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-369-300x23.png 300w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-369-65x5.png 65w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-369-225x17.png 225w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-369-350x27.png 350w\" sizes=\"auto, (max-width: 422px) 100vw, 422px\" \/><\/p>\n<ul>\n<li>Sulphur is added to soils is oxidized by bacterially mediated reactions to sulphuric acid<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-556\" src=\"http:\/\/esp16.epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/sites\/161\/2019\/03\/1-370.png\" alt=\"\" width=\"285\" height=\"56\" srcset=\"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-370.png 285w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-370-65x13.png 65w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-370-225x44.png 225w\" sizes=\"auto, (max-width: 285px) 100vw, 285px\" \/><strong>Nitrogen cycle<\/strong><\/p>\n<p style=\"text-align: justify\">Molecular nitrogen from air is fixed by soil organisms. Nitrogen enters into the bodies of soil organism and organic substances (humus) in soil through the process of decomposition and is further recycled through plants and animals.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-557\" src=\"http:\/\/esp16.epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/sites\/161\/2019\/03\/1-371.png\" alt=\"\" width=\"532\" height=\"298\" srcset=\"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-371.png 532w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-371-300x168.png 300w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-371-65x36.png 65w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-371-225x126.png 225w, https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-content\/uploads\/sites\/161\/2019\/03\/1-371-350x196.png 350w\" sizes=\"auto, (max-width: 532px) 100vw, 532px\" \/><\/p>\n<p><strong>\u00a0 \u00a0Figure 1: Nitrogen cycle<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: justify\"><em>Ammonification <\/em>is a process in which nitrogen containing organic molecules present in soil is converted into ammonium compounds. The amount of accumulation of ammonium varies with organism, soil and environment.<\/p>\n<p style=\"text-align: justify\"><em>Nitrification <\/em>is a process in which ammonium or other reduced forms of nitrogen are oxidized to nitrite and nitrate with the help of nitrifying agents including <em>nitrosomonas<\/em> and <em>nitrobacter.<\/em> The nitrate formed is utilized by crops and soil organisms for nutrition purpose.<\/p>\n<p style=\"text-align: justify\"><em>Denitrification <\/em>is a process of conversion of nitrite and nitrate into molecular nitrogen. It is caused by <em>Pseudomonas, Bacillus<\/em>,<em>Paracoccus. The a<\/em>naerobic condition of soil is conducive to denitrification<\/p>\n<p style=\"text-align: justify\">Nitrogen cycle leads to formation of microbial cells and organic matter in soil and its intermediate by-products leads to formation of humus in soil.<\/p>\n<\/div>\n<table>\n<tbody>\n<tr>\n<td><strong>you can view video on Soil- II (Essential, Macro and Micro Elements and Ion Exchange)<\/strong><\/td>\n<td><a href=\"https:\/\/youtu.be\/Xt0ojPhzNq0\" target=\"_blank\" rel=\"noopener\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-120\" src=\"http:\/\/epgpbooks.inflibnet.ac.in\/wp-content\/uploads\/2018\/11\/download.png\" alt=\"\" width=\"36\" height=\"36\" \/><\/a><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<div class=\"textbox exercises\">\n<h3>References:<\/h3>\n<ul>\n<li>Wild, A. Russell\u2019s \u201cSoil conditions and Plant growth\u201d, (11thedn) Longman Scientific and Technical, Harlow, Essex, UK, 1998.<\/li>\n<li>Epstein, E. \u201cMineral Nutrition of Plants: Principles and Perspectives\u201d, John Wiley &amp; Sons, Inc. New York USA, 1972.<\/li>\n<li>Marschner, H. \u201cMineral Nutrition of higher plants\u201d, Academic Press, London, U.K., 1995<\/li>\n<li>\u00a0Alexander, M. \u201cIntroduction to Soil Microbiology\u201d, 2ndedn, John Wiley &amp; Sons, New York, 1972 (Indian reprint, 1983, Wiley Eastern Limited, New Delhi).<\/li>\n<li>Biswas T. D. and Mukherjee S. K. \u201cTextbook of Soil Science\u201d, Tata Mc Graw- Hill Publishing Company Ltd, New Delhi, 1994.<\/li>\n<li>Chesworth, W. Ed., \u201cEncyclopedia of Soil Science\u201d, Springer, Dordrecht, The Netherlands, 2008.<\/li>\n<li>Manahan, S.E. \u201cEnvironmental Chemistry\u201d, CRC Press, Taylor &amp; Francis, New York, 2010.<\/li>\n<li><a href=\"http:\/\/www.marietta.edu\/~biol\/102\/ecosystem.html\">http:\/\/www.marietta.edu\/~biol\/102\/ecosystem.html<\/a><\/li>\n<li><a href=\"http:\/\/soil.hostweb.org.uk\/\">http:\/\/soil.hostweb.org.uk\/<\/a><\/li>\n<li><a href=\"http:\/\/landresources.montana.edu\/NM\/Modules\/mt44492.pdf\">http:\/\/landresources.montana.edu\/NM\/Modules\/mt44492.pdf<\/a><\/li>\n<\/ul>\n<\/div>\n<div><\/div>\n","protected":false},"author":3,"menu_order":25,"template":"","meta":{"pb_show_title":"on","pb_short_title":"","pb_subtitle":"","pb_authors":["prof-ajay-taneja"],"pb_section_license":""},"chapter-type":[],"contributor":[64],"license":[],"class_list":["post-553","chapter","type-chapter","status-publish","hentry","contributor-prof-ajay-taneja"],"part":3,"_links":{"self":[{"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/pressbooks\/v2\/chapters\/553","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/pressbooks\/v2\/chapters"}],"about":[{"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/wp\/v2\/types\/chapter"}],"author":[{"embeddable":true,"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/wp\/v2\/users\/3"}],"version-history":[{"count":7,"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/pressbooks\/v2\/chapters\/553\/revisions"}],"predecessor-version":[{"id":937,"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/pressbooks\/v2\/chapters\/553\/revisions\/937"}],"part":[{"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/pressbooks\/v2\/parts\/3"}],"metadata":[{"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/pressbooks\/v2\/chapters\/553\/metadata\/"}],"wp:attachment":[{"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/wp\/v2\/media?parent=553"}],"wp:term":[{"taxonomy":"chapter-type","embeddable":true,"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/pressbooks\/v2\/chapter-type?post=553"},{"taxonomy":"contributor","embeddable":true,"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/wp\/v2\/contributor?post=553"},{"taxonomy":"license","embeddable":true,"href":"https:\/\/ebooks.inflibnet.ac.in\/esp16\/wp-json\/wp\/v2\/license?post=553"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}